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Electrocatalytic Oxidation of HCOOH on an Electrodeposited AuPt Electrode: its Possible Application in Fuel Cells
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  • Electrocatalytic Oxidation of HCOOH on an Electrodeposited AuPt Electrode: its Possible Application in Fuel Cells
  • Electrocatalytic Oxidation of HCOOH on an Electrodeposited AuPt Electrode: its Possible Application in Fuel Cells
저자명
Uhm. Sung-Hyun,Jeon. Hong-Rae,Lee. Jae-Young
간행물명
Journal of electrochemical science and technology
권/호정보
2010년|1권 1호|pp.10-18 (9 pages)
발행정보
한국전기화학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

Controlled electrodeposition of dendritic nano-structured gold-platinum (AuPt) alloy onto an electrochemically pretreated carbon paper substrate was conducted in an attempt to improve catalyst utilization and to secure an electronic percolation network toward formic acid (FA) fuel cell application. The AuPt catalysts were obtained by potentiostatic deposition. AuPt catalysts synthesized as bimetallic alloys with 60% Au content exhibited the highest catalytic activity towards formic acid electro-oxidation. The origin of this high activity and the role of Au were evaluated, in particular, by XPS analysis. Polarization and stability measurements with 1 mg $cm^{-2}$ AuPt catalyst (only 0.4 mg $cm^{-2}$ Pt) showed 52 mW $cm^{-2}$ and sustainable performance using 3M formic acid and dry air at $40^{circ}C$.