Hysteresis is an effect by which the order of previous events influences the order of subsequent events. Hysteresis phenomenon of supersonic internal flows with shock waves has not yet been clarified satisfactorily. In the present study, experiments are carried out on internal flow in a supersonic nozzle to clarify the hysteresis phenomena for the shock waves. Flow visualization is carried out separately on the straight and divergent channels downstream of the nozzle throat section. Results obtained were compared with numerically simulated data. The results confirmed hysteresis phenomenon for shock wave in the Laval nozzle at a certain specific condition. The relationship between hysteresis phenomenon and the range of the rate of change of pressure ratio with time was shown experimentally. The existence of hysteretic behavior in the formation, both the location and strength, of shock wave in the straight part of the supersonic nozzle with a range of pressure ratio has also been confirmed numerically.