기관회원 [로그인]
소속기관에서 받은 아이디, 비밀번호를 입력해 주세요.
개인회원 [로그인]

비회원 구매시 입력하신 핸드폰번호를 입력해 주세요.
본인 인증 후 구매내역을 확인하실 수 있습니다.

회원가입
서지반출
Synthesis, Characterization, and Thermal Properties of New Organosoluble Poly(ester-imide)s Containing Ether Group
[STEP1]서지반출 형식 선택
파일형식
@
서지도구
SNS
기타
[STEP2]서지반출 정보 선택
  • 제목
  • URL
돌아가기
확인
취소
  • Synthesis, Characterization, and Thermal Properties of New Organosoluble Poly(ester-imide)s Containing Ether Group
  • Synthesis, Characterization, and Thermal Properties of New Organosoluble Poly(ester-imide)s Containing Ether Group
저자명
Faghihi. Khalil,Shabanian. Meisam,Emamdadi. Narjes
간행물명
Macromolecular research
권/호정보
2010년|18권 8호|pp.753-758 (6 pages)
발행정보
한국고분자학회
파일정보
정기간행물|ENG|
PDF텍스트
주제분야
기타
이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
서지반출

기타언어초록

A new series of aromatic poly(ester-imide)s (PEIs) 8a-f with 1,3-bis[4-aminophenoxy]propane moieties were prepared from the newly synthesized diacid monomer 6 with various aromatic diols 7a-f. The resulting polymers were fully characterized by Fourier transform infrared spectroscopy (FTIR) and $^1H$ nuclear magnetic resonance spectroscopy ($^1H$ NMR), elemental analysis, inherent viscosity, solubility tests, thermogravimetric analysis (TGA), and derivative of thermogravimetric (DTG) analysis. The PEIs had inherent viscosity ranging from 0.18 to 0.90 dL/g and were soluble in common organic solvents, such as N,N-dimethylacetamide (DMAc), N-methyl-2-pyrrolidone (NMP), N,N-dimethylformamide (DMF), and dimethyl sulfoxide (DMSO). They exhibited useful thermal properties associated with relatively moderate $T_gS$ (210-220$^{circ}C)$, 10% weight loss temperatures in excess of $380^{circ}C$, and char yields at $800^{circ}C$ in $N_2$ of up to 29%. Dicarboxylic acid 6 was synthesized from the reaction of 1,3-bis[3-aminophenoxy]propane 4 with trimellitic anhydride 5 in a solution of glacial acetic acid/pyridine (Py) at the refluxing temperature. 1,3-Bis[4-nitrophenoxyt]propane 3 was prepared by a reaction of 4-nitrophenol 1 with 1,3-dibromo propane 2 in a DMF solution. Dinitro 3 was reduced to diamine 4 using 10% Pd-C, ethanol and hydrazine monohydrate.