A hydrochemical comparative study of groundwater in uraniferous sedimentary rock of the Ogcheon belt was carried out to investigate the genetic relationship between uraniferous groundwater of Daejeon area and uraniferous sedimentary rocks of the Ogcheon zone. The groundwater shows weak alkaline pH values rangingfrom 6.4 to 8.1 and low Eh values ranging from -50 to 225 mV. The groundwaters to Ca-$HCO_3$ type that shows high concentration of $Ca^{2+}$ and $HCO_3^_$ due to the dissolution of carbonate mineral in limestone. The concentration of uranium in the groundwater was measured very low below $3.2{mu}g/L$, while it was detected as much as $1165{mu}g/L$ in the mine waste water. The low Eh value of groundwater is one of the main causes of low uranium concentration of groundwater in uraniferous sedimentary rocks in the Ogcheon belt. It is suggested that the uranium of groundwater in granitic region of Daejeon area was not mainly provided from uraniferous sedimentary rocks in the Ogcheon belt.