- 망간산화물 촉매를 이용한 악취제거
- ㆍ 저자명
- 서성규,윤형선,마충곤,류의,Seo. Seong-Gyu,Yoon. Hyung-Sun,Ma. Zhong-Kun,Liu. Yi
- ㆍ 간행물명
- 한국대기환경학회지
- ㆍ 권/호정보
- 2010년|26권 4호|pp.443-448 (6 pages)
- ㆍ 발행정보
- 한국대기환경학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
The objective of this study was to assess the catalytic activities of manganese oxide (MnO, $MnO_2$, $Mn_2O_3$, and $Mn_3O_4$) catalysts for odors (acetaldehyde and propionaldehyde) removal. We used a fixed bed reactor as the experimental apparatus and the catalytic performance were carried out over the temperature range of $200{sim}470^{circ}C$. The properties and performance of catalysts were characterized by the X-ray diffraction (XRD) and Brunauer Emmett Teller (BET). The catalytic activities of manganese oxide catalysts for acetaldehyde combustion were in the order of MnO < $MnO_2$ < $Mn_2O_3$ < $Mn_3O_4$, and it is similar to that of propionaldehyde combustion. We also confirmed that the reactions have well followed the kinetic model of Power-Rate Law and the reaction order (n) is 1 for both of the acetaldehyde and propionaldehyde combustion. In addition, the reaction activation energy of acetaldehyde and propionaldehyde combustion over $Mn_3O_4$ were found to be $72.42;kJmol^{-1}$ for 487~503 K and $51.14;kJmol^{-1}$ for 473~533 K, respectively.