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Mixed Electrolytes of Organic Solvents and Ionic Liquid for Rechargeable Lithium-Ion Batteries
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  • Mixed Electrolytes of Organic Solvents and Ionic Liquid for Rechargeable Lithium-Ion Batteries
  • Mixed Electrolytes of Organic Solvents and Ionic Liquid for Rechargeable Lithium-Ion Batteries
저자명
Choi. Ji-Ae,Shim. Eun-Gi,Scrosati. Bruno,Kim. Dong-Won
간행물명
Bulletin of the Korean Chemical Society
권/호정보
2010년|31권 11호|pp.3190-3194 (5 pages)
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대한화학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

Mixed electrolytes formed by the combination of 1-butyl-1-methylpyrrolidinium bis(trifluoromethanesulfonyl) imide (BMP-TFSI) ionic liquid and standard liquid electrolyte are prepared and characterized. Linear sweep voltammetry measurements demonstrate that these mixed systems exhibit a wide electrochemical stability window, allowing them to be suitable electrolyte for carbonaceous anode-based lithium-ion batteries. Lithium-ion cells composed of graphite anode and $LiCoO_2$ cathode are assembled using the mixed electrolytes, and their cycling performances are evaluated. The cell containing proper content of BMP-TFSI shows good cycling performance comparable to that of a cell assembled with organic electrolyte. The presence of BMP-TFSI in the mixed electrolyte contributes to the reduction of the flammability of electrolyte solution and the improvement of the thermal stability of charged $Li_{1-x}CoO_2$ in the electrolyte solution.