This study aims to implement the modeling of selected substances for the evaluation of Atmospheric Environmental Capacity by means of the data of 2006 atmospheric pollution substance emissions. As a result, it turned out that the substance with the concentration higher than Atmospheric Environmental standard concentration was NO2, and 17.6% of the total regions researched turned out to exceed the standard concentration. In addition, set was the targeted amount to be reduced in the areas where the upper limit of emission per unit lattice was exceeded, and the model was adopted accordingly. As a result, it turned out that about 80% of the actual emission should be reduced to meet the 2006 Atmospheric Environmental standard over the Daegu. In reality, it is impossible to reduce 80% of the actual emission. Thus, the same ratio of reduction was applied in all of the Daegu regions, and the modeling was applied. The results are as follows: When 30% was reduced, the level went down to 50 ppb, which is as high as 2006 Atmospheric Environmental standard; when 50% was reduced, the level went down to 30 ppb, which is as high as 2007 Atmospheric Environmental standard.