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Photovoltaic Behavior of Dye-sensitized Long TiO2 Nanotube Arrays
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  • Photovoltaic Behavior of Dye-sensitized Long TiO2 Nanotube Arrays
  • Photovoltaic Behavior of Dye-sensitized Long TiO2 Nanotube Arrays
저자명
Kim. Sang-Mo,Kim. Hark-Jin,Kim. Yong-Joo,Lim. Goo-Il,Choi. Young-Sik,Lee. Wan-In
간행물명
Bulletin of the Korean Chemical Society
권/호정보
2011년|32권 11호|pp.4035-4040 (6 pages)
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대한화학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

Long $TiO_2$ nanotube (NT) arrays, prepared by electrochemical anodization of Ti foils, have been utilized as dye-adsorbing electrodes in dye-sensitized solar cells (DSCs). By anodizing for 1-24 hr and subsequent annealing, highly crystallized and tightly-adhered NT arrays were tailored to 11-150 ${mu}m$ lengths, ~90 nm innerpore diameter and ~30 nm wall thickness. I-V curves revealed that the photovoltaic conversion efficiency (${eta}$) was proportional to the NT length up to 36 ${mu}m$. Beyond this length, the ) was proportional to the NT length up to ${eta}$ was still steadily increased, though at a much lower rate. For example, an ${eta}$ of 5.05% at 36 ${mu}m$ was increased to 6.18% at 150 ${mu}m$. Transient photoelectron spectroscopic analyses indicated that NT array-based DSCs revealed considerably higher electron diffusion coefficient ($D_e$) and life time (${ au}_e$) than those with $TiO_2$ nanoparticles (NP). Moreover, the electron diffusion lengths ($L_e$) of the photo-injected electrons were considerably larger than the corresponding NT lengths in all the cases, suggesting that electron transport in NT arrays is highly efficient, regardless of tube length.