In this paper, a design method of multi-tone signals for the measurement of adjacent-channel power-ratios on power amplifiers is suggested. Because most tests for power amplifiers in production are performed with single-tone signals, its testing accuracy is not guaranteed as the signal complexity increases. Therefore, the application of multi-tone signals to the testing is suggested by optimized complex coefficients of each tones for the best statistical similarity to the original modulated signal. From the verification, a 802.11a signal was replaced with a multi-tone signal of N=10, with the complex coefficients generated by the suggested method. The resulting measurements on the ACLR of 2.4 GHz power amplifier showed successful accuracy of less than 1 dB discrepancy.