The laminar natural convection of air in 2-D rectangular enclosure in which two opposing isothermal walls were kept at different temperatures is investigated numerically for Rayleigh number up to $10^6$. Computations were performed for the width-to-height ratios of 1, 2, and 4, and for the inclination angle range of $0^{circ}{leq}{ heta}{leq}90^{circ}$. For each aspect ratio, the influence of the inclination angle on the flow patterns and heat transfer rates were examined for $10^3{leq}Ra{leq}10^6$. It is found that the growth of secondary flow in the corners led to the decrease in overall heat transfer for small aspect ratio case, and the transition from a three-cell structure to a unicell flow pattern in large aspect ratio led to a step-like change in heat transfer. A new correlation of mean Nusselt number is presented for the vertical case of ${ heta}=90^{circ}$.