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Low-temperature Synthesis of Highly Crystalline BaxSr1-xTiO3 Nanoparticles in Aqueous Medium
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  • Low-temperature Synthesis of Highly Crystalline BaxSr1-xTiO3 Nanoparticles in Aqueous Medium
  • Low-temperature Synthesis of Highly Crystalline BaxSr1-xTiO3 Nanoparticles in Aqueous Medium
저자명
Kim. Yong-Joo,Rawal. Sher Bahadur,Sung. Sang-Do,Lee. Wan-In
간행물명
Bulletin of the Korean Chemical Society
권/호정보
2011년|32권 1호|pp.141-144 (4 pages)
발행정보
대한화학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
서지반출

기타언어초록

We report the synthesis of $SrTiO_3$, $BaTiO_3$ and $Ba_xSr_{1-x}TiO_3$ (BST) nanoparticles (NPs) in various compositions (x = 0.25, 0.5 and 0.75) by an inorganic sol-gel method under a basic condition. Highly crystalline nanoparticles were formed at the reaction temperature of 25 - $100^{circ}C$ from a stabilized titanium alkoxide in tetramethylammonium hydroxide (TMAH) and barium or strontium acetate in aqueous solution. Morphology and particle structure of the synthesized BST NPs were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD) and transmission electron microscopy (TEM). The BST nanoparticles in various compositions were monodispersed without mutual aggregation, and their average sizes were in the range of 70 - 80 nm. Furthermore, they showed highly crystallized perovskite phase over the whole composition range from $SrTiO_3$ to $BaTiO_3$. We also proposed a mechanism for the low-temperature formation of BST NPs.