- 유리 및 결정화 유리 골 시멘트에서 DCPD의 형성 및 수산화 아파타이트로의 전환
- ㆍ 저자명
- 임형봉,김철영,Lim. Hyung-Bong,Kim. Cheol-Young
- ㆍ 간행물명
- 한국세라믹학회지
- ㆍ 권/호정보
- 2011년|48권 1호|pp.26-33 (8 pages)
- ㆍ 발행정보
- 한국세라믹학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
The glass in the system of CaO-$SiO_2-P_2O_5$ and the corresponding glass-ceramics are prepared for bone cements and the behaviors of the hardening and hydroxyapatite formation were studied for the glass and glass-ceramic powders. The glass crystallized into apatite, $alpha$-wollastonite and $eta$-wollastonite depending on the glass composition when they were heat-treated at $950^{circ}C$ for 4 h. A DCPD (dicalcium phosphate dihydrate : $CaHPO_4{cdot}2H_2O$) was developed when the prepared glass and glass-ceramic powders were mixed with 3M-$H_3PO_4$ solution. The DCPD (Ca/P=1.0) transformed to HAp (Ca/P=1.67) when the bone cement was soaked in simulated body fluid (SBF), and this HAp formation strongly depended on the releasing capacity of $Ca^{2+}$ ions from the glass and glass-ceramic cements. The glass-ceramic bone cement containing $alpha$-wollastonite crystals showed faster transformation of DCPD to HAp than other glass-ceramics containing $alpha$- and $eta$-wollastonite crystals. No hydroxyapatite was observed when the glass-ceramic bone cement containing apatite crystals (36P6C) was soaked in SBF even for 1 month, because no $Ca^{2+}$ ion can be released from the stable apatite crystals.