In the power system with an electric storage system that can increase utilization rate of the source of such new renewable energy, this paper introduces the approach on the daily unit commitment scheduling that determines simultaneously optimum operational condition and output of thermal generators and electric storage device. The unit commitment is one of the most important issues in economic operation and security of short-term operational plan of the power system. It is to determine on/off status of generator to minimize operational cost during the given period. The committed generator should satisfy various operational limitation such as estimated demand by system, spinning reserve condition within minimum operational cost. In order to determine on/off or charge/discharge/idle condition and output level of units and electric storage system, the MILP(Mixed Integer Linear Programming) is suggested. The proposed approach is the mixed method between LP(Linear Programming) and IP(integer programming) which seeks the value of real number and integer that maximize or minimize function objective within given condition. The daily unit commitment problem with the electric storage system is applied to MILP algorithm through linearization and formulation process. The proposed approach is applied to the test system.