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Morphology and Charge Transport Properties of Chemically Synthesized Polyaniline-poly(ε-caprolactone) Polymer Films
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  • Morphology and Charge Transport Properties of Chemically Synthesized Polyaniline-poly(ε-caprolactone) Polymer Films
  • Morphology and Charge Transport Properties of Chemically Synthesized Polyaniline-poly(ε-caprolactone) Polymer Films
저자명
Basavaraja. C.,Kim. Dae-Gun,Kim. Won-Jeong,Kim. Ji-Hyun,Huh. Do-Sung
간행물명
Bulletin of the Korean Chemical Society
권/호정보
2011년|32권 3호|pp.927-933 (7 pages)
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대한화학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

Conducting polyaniline-poly($varepsilon$-caprolactone) polymer composites were synthesized via in situ deposition techniques. By dissolving different weight percentages of poly($varepsilon$-caprolactone) (PCL) (10%, 20%, 30%, 40%, and 50%), the oxidative polymerization of aniline was achieved using ammonium persulfate as an oxidant. FTIR, UV-vis spectra, and X-ray diffraction studies support a strong interaction between polyaniline (PANI) and PCL. Structural morphology of the PANI-PCL polymer composites was studied using scanned electron microscopy (SEM) and transmittance electron microscopy (TEM), and thermal stability was analyzed by thermogravimetric analysis (TGA) technique. The temperature-dependent DC conductivity of PANI-PCL polymer composite films was studied in the range of 305-475 K, which revealed a semiconducting behavior in the transport properties of the polymer films. Conductivity increased with the increase of PCL in below critical level, however conductivity of the polymer film was decreased with increase of PCL concentration higher than the critical value.