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Effect of Hydrophobic Ionic Liquid Loading on Characteristics and Electromechanical Performance of Cellulose
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  • Effect of Hydrophobic Ionic Liquid Loading on Characteristics and Electromechanical Performance of Cellulose
  • Effect of Hydrophobic Ionic Liquid Loading on Characteristics and Electromechanical Performance of Cellulose
저자명
Mahadeva. Suresha K.,Kim. Jae-Hwan,Jo. Chul-Hee
간행물명
International journal of precision engineering and manufacturing
권/호정보
2011년|12권 1호|pp.47-52 (6 pages)
발행정보
한국정밀공학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

This paper presents the characteristics and electromechanical performance of hydrophobic ionic liquid namely; 1-butyl-3-methylimidazolium hexafluorophosphate ($BMIPF_6$) loaded cellulose. Different amount of $BMIPF_6$ is loaded in to cellulose via solution blending during its dissolution and regeneration in trifluoroacetic acid Influence of $BMIPF_6$ loading on characteristics, mechanical and electromechanical properties are assessed by scanning electron microscopy, X-ray diffractograms, thermogravimetric analysis, tensile test and bending displacement tests. Experimental results show that thermal degradation temperature of the cellulose tends to decrease with increasing the BMIPF6 loading, which may be due to weakening of the intra- and intermolecular hydrogen bonds of cellulose upon addition of $BMIPF_6$. X-ray diffraction analysis showed that the raise of the $BMIPF_6$ content resulted in enormous reduction of peak intensities at $2{ heta}=12^{circ}$ and $20.85^{circ}$. This might be due to irregular structures caused by the introduction of $BMIPF_6$ molecules in to cellulose, results in lower crystallinity as well as the mechanical properties, $BMIPF_6$ loaded cellulose actuator shows a maximum bending displacement output of 4 mm with comparatively better durability for prolonged time under relatively low humid condition.