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Effects of Titanium Impurity on the Crystallographic and Spin-rotation Transitions of FeS
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  • Effects of Titanium Impurity on the Crystallographic and Spin-rotation Transitions of FeS
  • Effects of Titanium Impurity on the Crystallographic and Spin-rotation Transitions of FeS
저자명
Nam. Hyo-Duk,Kim. Eng-Chan
간행물명
Journal of magnetics
권/호정보
2011년|16권 1호|pp.23-26 (4 pages)
발행정보
한국자기학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

The effects of titanium ions on the crystallographic and spin-rotation transitions in iron sulfide have been examined by M$"{o}$ssbauer spectroscopy in the temperature range of 78 to 600 K. It is noted that the titanium impurity of $Ti_{0.02}Fe_{0.98}S$ affects both the crystallographic and spin-rotation transitions of the iron sulfide. 2% impurity of $Ti^{2+}$ in FeS causes the increase in the difference between the spin rotation and ${alpha}$ transition temperature by as much as 10 K compared with that for FeS. Both 1c and 2c structures coexist in the range between the ${alpha}$ transition temperature and approximately 26 K, with a smaller hyperfine field corresponding to the 1c structure. The spin-rotation temperature for $Ti_{0.02}Fe_{0.98}S$ was measured to be 365 K, which is 10 K lower than the ${alpha}$ transition temperature. By the 2% impurity of $Ti^{2+}$ in FeS the N$'{e}$el temperature appreciably is not affected.