기관회원 [로그인]
소속기관에서 받은 아이디, 비밀번호를 입력해 주세요.
개인회원 [로그인]

비회원 구매시 입력하신 핸드폰번호를 입력해 주세요.
본인 인증 후 구매내역을 확인하실 수 있습니다.

회원가입
서지반출
Effect of TiO2 Nanotube Length on Photocatalytic Activity with Different Light Intensities: Cr(VI) Reduction and Hydrogen Production
[STEP1]서지반출 형식 선택
파일형식
@
서지도구
SNS
기타
[STEP2]서지반출 정보 선택
  • 제목
  • URL
돌아가기
확인
취소
  • Effect of TiO2 Nanotube Length on Photocatalytic Activity with Different Light Intensities: Cr(VI) Reduction and Hydrogen Production
  • Effect of TiO2 Nanotube Length on Photocatalytic Activity with Different Light Intensities: Cr(VI) Reduction and Hydrogen Production
저자명
주현규,심은정,이재민,윤재경,Joo. Hyun-Ku,Shim. Eun-Jung,Lee. Jae-Min,Yoon. Jae-Kyung
간행물명
한국수소 및 신에너지학회 논문집
권/호정보
2011년|22권 4호|pp.432-442 (11 pages)
발행정보
한국수소및신에너지학회
파일정보
정기간행물|ENG|
PDF텍스트
주제분야
기타
이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
서지반출

기타언어초록

Anodized tubular $TiO_2$ electrodes (ATTEs) with three noticeably different lengths are prepared to determine their optimum length for the photo-driven activity in the reaction of Cr(VI) reduction and hydrogen evolution. The ATTEs with ethylene glycol have longer $TiO_2$ tubes (7-15.6 ${mu}m$) than those with hydrfluoric acid (0.6-0.8 ${mu}m$). These samples, which differ only in the length of the tubes, with a wall thickness of ca. 20 nm, consist mainly of an anatase crystalline phase after heat treatment at $650^{circ}C$, since the anatase crystallites at the tube walls do not undergo transformation into rutile phase, due to the constraints imposed by the wall thickness. Among them, the medium size (ca. 8 ${mu}m$) tubes provide the optimum conditions, irrespective of the light intensity, which is explained in terms of the correlation between the amount of photons and the adsorbed electron acceptors and their location. Photocatalytic Cr(VI) reduction leads to ca. 60% reduction of Cr(VI) even under 1 sun irradiation with the medium-sized anodized $TiO_2$ tubes, but only ca. 20% with the short- and long-sized tubes. For hydrogen evolution, tubes longer than 8 ${mu}m$ do not exhibit better performance with any light intensity.