Thermal spray technology has been used in many industrial application. Especially, thermal spray coating have been employed with the purposes of achieving better resistances in abrasion, heat and corrosion. In the previous studies on the thermal spray coating, thermal spray characteristics from the perspective of combustion engineering have not been investigated sufficiently, while the material characteristics of the coated substrates have been investigated widely. In this study, the effect of spray particles on the flame behavior was experimentally investigated. The amount of the injected particles was measured using the light scattering method and the temperature of the particles was estimated using a two-color method. Various flame-spray interactions were observed and it was found that the high temperature zone near the flame is elongated by particles density. Based on these results, the applicability of the light scattering method and the two-color method was discussed.