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A Study on Three Factors Influencing Uptake Rates of Nitric Acid onto Dust Particles
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  • A Study on Three Factors Influencing Uptake Rates of Nitric Acid onto Dust Particles
  • A Study on Three Factors Influencing Uptake Rates of Nitric Acid onto Dust Particles
저자명
Song. Chul-Han,Kim. Chung-Man
간행물명
Asian journal of atmospheric environment
권/호정보
2011년|5권 2호|pp.97-104 (8 pages)
발행정보
한국대기환경학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

Recent studies have indicated that the observed nitric acid ($HNO_3$) uptake rates ($R_{HNO_3}$) onto dust particles are much slower than $R_{HNO_3}$ used in the previous modeling studies. Three factors that possibly affect $R_{HNO_3}$ onto dust particles are discussed in this study: (1) the magnitude of reaction probability of $HNO_3$ (${gamma}_{HNO_3}$), (2) aerosol surface areas, and (3) gas-phase $HNO_3$ mixing ratio. Through the discussion presented here, it is shown that the use of accurate ${gamma}_{HNO_3}$ is of primary importance. We suggest that the use of ${gamma}_{HNO_3}$ values between $sim10^{-3}$ and $sim10^{-5}$ produces more realistic results than the use of ${gamma}_{HNO_3}$ values between $sim10^{-1}$ and $sim10^{-2}$ does, more accurately modeling the nitrate formation characteristics on/in dust particles. We also discuss two different types of aerosol surface area, active and geometric, since the use of different aerosol surface areas often leads to an erroneous result in $R_{HNO_3}$. In addition, the levels of the gas-phase $HNO_3$ are investigated with the example cases of TRACE-P DC-8 flights in East Asia. The $HNO_3$ levels were found to be relatively high, indicating that they can not limit nitrate formation in dust particles.