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고상법에 의한 Zn2SiO4:Mn2+녹색 형광체의 제조와 특성에 관한 연구
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  • 고상법에 의한 Zn2SiO4:Mn2+녹색 형광체의 제조와 특성에 관한 연구
저자명
유현희,원형일,원창환,Yoo. Hyeon-Hee,Won. Hyung-Il,Won. Chang-Whan
간행물명
한국재료학회지
권/호정보
2011년|21권 6호|pp.352-356 (5 pages)
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한국재료학회
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정기간행물|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

[ $Zn_{2(1-x)}Mn_xSiO_4$ ]$0.07{leq}x{leq}0.15$) green phosphor was prepared by solid state reaction. The first heating was at $900^{circ}C-1250^{circ}C$ in air for 3 hours and the second heating was at $900^{circ}C$ in $N_2/H_2$(95%/5%) for 2 hours. The size effect of $SiO_2$ in forming $Zn_2SiO_4$ was investigated. The temperature for obtaining single phase $Zn_2SiO_4$ was lowered from $1100^{circ}C$ to $1000^{circ}C$ by decreasing the $SiO_2$ particle size from micro size to submicro size. The effect of the activators for the Photoluminescence (PL) intensity of $Zn_2SiO_4:Mn^{2+}$ was also investigated. The PL intensity properties of the phosphors were investigated under vacuum ultraviolet excitation (147 nm). The emission spectrum peak was between 520 nm and 530 nm, which was involved in green emission area. $MnCl_2{cdot}4H_2O$, the activator source, was more effective in providing high emission intensity than $MnCO_3$. The optimum conditions for the best optical properties of $Zn_2SiO_4:Mn^{2+}$ were at x = 0.11 and $1100^{circ}C$. In these conditions, the phosphor particle shape was well dispersed spherical and its size was 200 nm.