- 순환전류 전압법을 이용한 이산화황 피독 PEMFC 단위전지의 성능 회복
- ㆍ 저자명
- 이수,진석환,Lee. Soo,Jin. Seok-Hwan
- ㆍ 간행물명
- 한국유화학회지
- ㆍ 권/호정보
- 2011년|28권 4호|pp.497-501 (5 pages)
- ㆍ 발행정보
- 한국유화학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
Polymer electrolyte membrane fuel cell (PEMFC) performance degrade when sulfur dioxide is present in the fuel hydrogen gas, this is referred as $SO_2$ poisoning. This paper reveals $SO_2$ poisoning on PEMFC cathode part by measuring electrical performance of single cell under 1 ppm and 5 ppm on $SO_2$ gas operating. The security of $SO_2$ poisoning depended on $SO_2$ concentration under the best operating conditions($65^{circ}C$ of cell temperature and 100% of relative humidity between anode and cathode). $SO_2$ adsorption occured on the surface of catalyst layer on membrane electrode assembly (MEA), In addition, MEA poisoning by $SO_2$ was cumulative but reversible. After poisoning within 5 ppm $SO_2$ for 1hr, the electrical performance of PEMFC was found to recover up to about 93% by cyclic voltametry scan.