The battery capacity of electric/hybrid vehicle is much larger than present automobile. For that reason, the connector of Green Car should be designed to transmit the high-electric voltage. In addition, the electromagnetic wave should be shielded to protect communication and signal circuits. In this study, shielding performance of the connector was analyzed through electromagnetic shield analysis, and a connector of Green Car was designed using thermoelectrical analysis, which is capable of transmitting the high-electric power. In the design of connector structure, the improved stability and workability was considered.