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Preparation by Suspension Polymerization and Characterization of Polystyrene (PS)-Poly(methyl methacrylate) (PMMA) Core-Shell Nanocomposites
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  • Preparation by Suspension Polymerization and Characterization of Polystyrene (PS)-Poly(methyl methacrylate) (PMMA) Core-Shell Nanocomposites
  • Preparation by Suspension Polymerization and Characterization of Polystyrene (PS)-Poly(methyl methacrylate) (PMMA) Core-Shell Nanocomposites
저자명
Debnath. Dibyendu,Khatua. B.B.
간행물명
Macromolecular research
권/호정보
2011년|19권 6호|pp.519-527 (9 pages)
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한국고분자학회
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정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

The effect of nanoclay on the thermal stability of polystyrene (PS)-poly(methyl methacrylate) (PMMA) core-shell nanocomposites morphology prepared by in situ suspension polymerization technique was investigated. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) revealed the formation of a PS-PMMA core-shell structure, both in the absence and presence of the clay. Wide angle X-ray diffraction (WAXD) indicated the formation of a highly intercalated expanded clay morphology in the core-shell composite particles irrespective of the location of the clay in the nanocomposites. Thermo gravimetric analysis (TGA) indicated an improvement in the thermal stability of the core-shell nanocomposites compared to that of the neat PS-PMMA core-shell one. Differential scanning calorimetry (DSC) showed that the core-shell nanocomposite particles containing the clay had a higher glass transition ($T_g$) temperature than the neat PS-PMMA core-shell composites particles. On the other hand, the improvement in the thermal stability of the PS-PMMA core-shell composites was found to depend strongly on the location and loading of the clay in the core-shell nanocomposites. FTIR indicated a probable interaction between the carbonyl (>C=O) group of PMMA and hydroxyl (-OH) group of the clay.