Cloud computing emerges as a new paradigm for deploying, managing and offering IT resources as a service anytime, anywhere on any devices. Cloud computing data center stores many IT resources through resource integration. So cloud computing system has to be designed by technology and policy to make effective use of IT resources. In other words, cloud vendor has to provide high quality services to all user and mitigate the dissipation of IT resources. However, vendors need to predict the performance of cloud services and the use of IT resources before releasing cloud service. For solving the problem, this research presents cloud service modeling on network environment and evaluation index for availability optimization of cloud service. We also study how to optimize an amount of requested cloud service and performance of datacenter using CloudSim toolkit.