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Synthesis of One-dimensional Spinel LiMn2O4 Nanostructures as a Positive Electrode in Lithium Ion Battery
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  • Synthesis of One-dimensional Spinel LiMn2O4 Nanostructures as a Positive Electrode in Lithium Ion Battery
  • Synthesis of One-dimensional Spinel LiMn2O4 Nanostructures as a Positive Electrode in Lithium Ion Battery
저자명
Lee. Hyun-Wook,Muralidharan. P.,Kim. Do-Kyung
간행물명
한국세라믹학회지
권/호정보
2011년|48권 5호|pp.379-383 (5 pages)
발행정보
한국세라믹학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

This paper presents the synthesis of one-dimensional spinel $LiMn_2O_4$ nanostructures using a facile and scalable two-step process. $LiMn_2O_4$ nanorods with average diameter of 100 nm and length of 1.5 ${mu}m$ have been prepared by solid-state lithiation of hydrothermally synthesized ${eta}$-$MnO_2$ nanorods. $LiMn_2O_4$ nanowires with diameter of 10 nm and length of several micrometers have been fabricated via solid-state lithiation of ${eta}$-$MnO_2$ nanowires. The precursors have been lithiated with LiOH and reaction temperature and pressure have been controlled. The complete structural transformation to cubic phase and the maintenance of 1-D nanostructure morphology have been evaluated by XRD, SEM, and TEM analysis. The size distribution of the spinel $LiMn_2O_4$ nanorods/wires has been similar to the $MnO_2$ precursors. By control of reaction pressure, cubic 1-D spinel $LiMn_2O_4$ nanostructures have been fabricated from tetragonal $MnO_2$ precursors even below $500^{circ}C$.