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The Effect of a Sol-gel Formed TiO2 Blocking Layer on the Efficiency of Dye-sensitized Solar Cells
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  • The Effect of a Sol-gel Formed TiO2 Blocking Layer on the Efficiency of Dye-sensitized Solar Cells
  • The Effect of a Sol-gel Formed TiO2 Blocking Layer on the Efficiency of Dye-sensitized Solar Cells
저자명
Cho. Tae-Yeon,Yoon. Soon-Gil,Sekhon. S.S.,Kang. Man-Gu,Han. Chi-Hwan
간행물명
Bulletin of the Korean Chemical Society
권/호정보
2011년|32권 10호|pp.3629-3633 (5 pages)
발행정보
대한화학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

The effect of a dense $TiO_2$ blocking layer prepared using the sol-gel method on the performance of dye-sensitized solar cells was studied. The blocking layer formed directly on the working electrode, separated it from the electrolyte, and prevented the back transfer of electrons from the electrode to the electrolyte. The dyesensitized solar cells were prepared with a working electrode of fluorine-doped tin oxide glass coated with a blocking layer of dense $TiO_2$, a dye-attached mesoporous $TiO_2$ film, and a nano-gel electrolyte, and a counter electrode of Pt-deposited FTO glass. The gel processing conditions and heat treatment temperature for blocking layer formation affected the morphology and performance of the cells, and their optimal values were determined. The introduction of the blocking layer increased the conversion efficiency of the cell by 7.37% for the cell without a blocking layer to 8.55% for the cell with a dense $TiO_2$ blocking layer, under standard illumination conditions. The short-circuit current density ($J_{sc}$) and open-circuit voltage ($V_{oc}$) also were increased by the addition of a dense $TiO_2$ blocking layer.