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Preparation and Characterization of Silver Nanoparticles Embedded in Silica Sol Particles
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  • Preparation and Characterization of Silver Nanoparticles Embedded in Silica Sol Particles
  • Preparation and Characterization of Silver Nanoparticles Embedded in Silica Sol Particles
저자명
Kang. Byung-Kyu,Son. Dong-Min,Kim. You-Hyuk
간행물명
Bulletin of the Korean Chemical Society
권/호정보
2011년|32권 10호|pp.3707-3711 (5 pages)
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대한화학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
서지반출

기타언어초록

Silver nanoparticles coated with silica can be obtained by the reduction of $AgNO_3$ with hydrazine in the presence of NaOH-stabilized, active silicic acid (polysilicic acid). The size of the silver nanoparticles and the silica shell thicknesses were affected by varying the hydrazine content, the active silicic acid content and the experimental method (e.g. hydrothermal method). Typically, silver nanoparticles sized around 40 nm were aggregated, connected by silica. The presence of peaks centered around 400 nm in UV-vis spectra corresponds to the surface plasmon resonance of silver nanoparticles. The size of the aggregated silver nanoparticles increased with increasing hydrazine concentration. Under hydrothermal conditions at $150^{circ}C$ the formation of individual silica particles was observed and the sizes of the silver nanoparticles were reduced. The hydrothermal treatment of silver nanoparticles at $180^{circ}C$ gives a well-defined Ag@$SiO_2$ core-shell in aggregated silica sol particles. The absorption band observed at around 412 nm were red-shifted with respect to the uncoated silver nanoparticles (${lambda}_{max}$ = 399 nm) due to the larger refractive index of silica compared to that of water. The formation of silver nanoparticles coated with silica is confirmed by UV-visible absorption spectra, transmission electron microscopy (TEM) and energy-dispersive spectroscopy (EDS) data.