- 황화수소 피독이 고분자전해질 막 연료전지의 성능에 미치는 영향
- ㆍ 저자명
- 이수,진석환,김상명,Lee. Soo,Jin. Seok-Hwan,Kim. Sang-Myoung
- ㆍ 간행물명
- 한국유화학회지
- ㆍ 권/호정보
- 2011년|28권 1호|pp.57-63 (7 pages)
- ㆍ 발행정보
- 한국유화학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
Polymer electrolyte membrane fuel cell (PEMFC) performance degrades when hydrogen sulfide ($H_2S$) is present in the fuel hydrogen gas; this is referred to as $H_2S$ poisoning. This paper reveals $H_2S$ poisoning on PEMFC by measuring electrical performance of single cell FC under various operating conditions. The severity of $H_2S$ poisoning depended on $H_2S$ concentration under best operating conditions($65^{circ}C$ of cell temperature and 100% of anode humidification). $H_2S$ adsorption occured on the surface of catalyst layer on MEA, but not on the gas diffusion layer(GDL) by analyzing SEM/EDX data. In addition, MEA poisoning by $H_2S$ was cumulative but reversible. After poisoning for less than 150 min, performance of PEMFC was recovered up to 80% by just inert nitrogen gas purging.