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기체-액체 혼합조건에 따른 Engineered PCC의 형태학적 분석
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  • 기체-액체 혼합조건에 따른 Engineered PCC의 형태학적 분석
저자명
이태주,서진호,김형진,Lee. Tai-Ju,Seo. Jin-Ho,Kim. Hyoung-Jin
간행물명
펄프 종이기술
권/호정보
2011년|43권 3호|pp.113-120 (8 pages)
발행정보
한국펄프종이공학회
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

Precipitated calcium carbonate(PCC), particularly calcite crystal, is extensively used as a pigment, filler or extender in various industries such as paper, paint, textile, detergents, adhesives, rubber and plastics, food, cosmetics, and biomaterials. PCC is conventionally produced through the gas-liquid carbonation process, which consists on bubbling gaseous $CO_2$ through a concentrated calcium hydroxide slurry. This study is aimed to find some factors for controlling the morphology of engineered PCC in lab-scaled mixing batch. The experimental designs were based on temperature variables, $Ca(OH)_2$ concentration, $CO_2$ flow rate, and electrical conductivity. The model of engineered PCC morphology was finally controlled by adjustment of electrical conductivity(6.0~7.0 mS/cm) and $Ca(OH)_2$ concentration(10 g/L). Orthorhombic calcite crystals were mostly created at high concentration and electrical conductivity conditions because the increased ratio of $Ca^{2+}$ and $CO{_3}^{2-}$ ions affects the growth rate of orthorhombic faces. Excess calcium spices were contributed to the growth of faces in calcium carbonate crystal, and the non-stoichiometric reaction was occurred between $Ca^{2+}$ and $CO{_3}^{2-}$ ions during carbonation process.