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Enhanced Sintering Behavior and Electrical Properties of Single Phase BiFeO3 Prepared by Attrition Milling and Conventional Sintering
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  • Enhanced Sintering Behavior and Electrical Properties of Single Phase BiFeO3 Prepared by Attrition Milling and Conventional Sintering
  • Enhanced Sintering Behavior and Electrical Properties of Single Phase BiFeO3 Prepared by Attrition Milling and Conventional Sintering
저자명
Jeon. Nari,Moon. Kyoung-Seok,Rout. Dibyranjan,Kang. Suk-Joong L.
간행물명
한국세라믹학회지
권/호정보
2012년|49권 6호|pp.485-492 (8 pages)
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한국세라믹학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

Dense and single phase $BiFeO_3$ (BFO) ceramics were prepared using attrition milled calcined (coarse) powders of an average particle size of ${approx}3{mu}m$ by conventional sintering process. A relative density of ${approx}96%$ with average grain size $7.3{mu}m$ was obtained when the powder compacts were sintered at $850^{circ}C$ even for a shorter duration of 10 min. In contrast, densification barely occurred at $800^{circ}C$ for up to 12 h rather the microstruce showed the growth of abnormal grains. The grain growth behavior at different temperatures is discussed in terms of nonlinear growth rates with respect to the driving force. The sample sintered at $850^{circ}C$ for 12 h showed enhanced electrical properties with leakage current density of $4{ imes}10^{-7}A/cm^2$ at 1 kV/cm, remnant polarization $2P_r$ of $8{mu}C/cm^2$ at 20 kV/cm, and minimal dissipation factor (tan ${delta}$) of ~0.025 at $10^6$ Hz. These values are comparable to the previously reported values obtained using unconventional sintering techniques such as spark plasma sintering and rapid liquid phase sintering.