- CuO 세라믹스의 소결 온도 및 분위기에 따른 미세구조와 수축거동 변화
- ㆍ 저자명
- 송주현,이정아,이준형,허영우,김정주,Song. Ju-Hyun,Lee. Jung-A,Lee. Joon-Hyung,Heo. Young-Woo,Kim. Jeong-Joo
- ㆍ 간행물명
- 한국세라믹학회지
- ㆍ 권/호정보
- 2012년|49권 6호|pp.528-534 (7 pages)
- ㆍ 발행정보
- 한국세라믹학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
In this study, the densification behavior and microstructural evolution of CuO were examined when this material was sintered at different temperatures in $O_2$, air and Ar atmospheres. The CuO samples maintained their phases even after prolonged sintering at $900-1100^{circ}C$ in an oxygen atmosphere. When sintering in air, the densification was faster than it was when sintering in oxygen. However, when the samples were sintered at $1100^{circ}C$, large pores were observed in the sample due to the phase transformation from CuO to $Cu_2O$ which accompanies the generation of oxygen gas. The pore channels in the sample became narrower as the sintering time increased, eventually undergoing a Rayleigh breakup and forming discrete isolated pores. On the other hand, CuO sintering in Ar did not contribute to the densification, as all CuO samples underwent a phase transformation to $Cu_2O$ during the heating process.