As DME (Dimethyl ether) is the one of the future possible massive energy sources synthesized from natural gas, KOGAS has been doing to obtain overseas resources to meet the domestic needs. and tried to build new DME FPSO ship. This paper presents that it can help for the DME storage tank designers and storage management engineers doing proper work by understood the evaporation phenomena and pressure change of DME by thermal intake in storage tank. The experimental result shows that the evaporation rate and pressure are increased with higher liquid filling level. The proper DME liquid filling level in tank is obtained as lower than full 98% volume of tank in case of storing longer than a day, because the pressure is increased rapidly with full 98% filled level of storage tank.