This paper introduces a technique for resolving amino acids that combines the advantages of the conventional CSP (chiral stationary phase) method with the CMPA (chiral mobile phase additive) method. A commercially available chiral crown ether column, CROWNPAK CR(+), was used as the CSP and three cyclodextrins (${eta}$-CD, ${gamma}$-CD, HP-${eta}$-CD) were used as the mobile phase additives. Chromatographic resolution was performed at $25^{circ}C$ and $50^{circ}C$ with or without sonication. A comparison of the chromatographic results under ultrasonic conditions with those under non-ultrasonic conditions showed that ultrasound decreased the elution time and enantioselectivity at all temperatures. In the case of the ${eta}$-CD mobile phase additive, the elution time and enantioselectivity under ultrasonic condition were significantly higher than under non-sonic condition at all temperatures. Commercially available Chiralpak AD, Whelk-O2 and Pirkle 1-J columns were used as CSPs to examine more meticulously the effects of ultrasonication and temperature on the optical resolution. The optical resolution of some chiral samples analyzed at $25^{circ}C$ and $50^{circ}C$ with or without sonication was compared. As in the previous case, the enantioselectivity was lower at $25^{circ}C$ but similar enantioselectivity was observed at $50^{circ}C$.