To address the problem of global warming, consumption of cement, the main material of concrete, should be decreased. Unfortunately, when industrial by-products are used in large quantities as admixture, the early age strength of concrete will be decreased, reducing its viability for use in concrete structures. Therefore, in this study, the application of an ionization accelerator and alkaline activator as addition agent of superplasticizer were investigated to secure a similar early age strength to that of normal concrete, thus increasing the viability of low cement concrete. Through the investigation, it was found that specimens that used a combination of Alkaline-activator (Na2Sio3) and ionization accelerator (Amine) had the highest early and long-age compressive strength. From this, we can determine an appropriate range of application of superplasticizer to improve early-age compressive strength of low cement concrete.