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Experimental Study for the Identification of the Nascent Product of OH Heterogeneous Reaction with NaCl using Chemical Ionization Mass Spectrometry
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  • Experimental Study for the Identification of the Nascent Product of OH Heterogeneous Reaction with NaCl using Chemical Ionization Mass Spectrometry
  • Experimental Study for the Identification of the Nascent Product of OH Heterogeneous Reaction with NaCl using Chemical Ionization Mass Spectrometry
저자명
Park. Jong-Ho,Ivanov. Andrey V.,Molina. Mario J.
간행물명
Mass spectrometry letters
권/호정보
2012년|3권 4호|pp.108-111 (4 pages)
발행정보
한국질량분석학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

An experimental study on the nascent product of the OH heterogeneous reaction with NaCl was performed under dry and wet conditions using a bead-filled flow tube system coupled to a high-pressure chemical ionization mass spectrometer. The ozone concentration in the flow tube for the atomic hydrogen removal was varied in order to control the conversion reaction of molecular chlorine into HCl for the identification of the nascent product. The mass spectrometric observation was that the $O_3$ introduction reduced the concentration HCl, while it increased the concentration of $Cl_2$ and ClO. Based on the experimental results, we suggest that the nascent product of the titled reaction is gaseous $Cl_2$, which is followed by fast conversion into HCl in presence of H. No significant difference in the concentration profile between under dry and wet (RH = 2%) conditions was observed.