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Synthesis and Performance of Li2MnSiO4 as an Electrode Material for Hybrid Supercapacitor Applications
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  • Synthesis and Performance of Li2MnSiO4 as an Electrode Material for Hybrid Supercapacitor Applications
  • Synthesis and Performance of Li2MnSiO4 as an Electrode Material for Hybrid Supercapacitor Applications
저자명
Karthikeyan. K.,Amaresh. S.,Son. J.N.,Lee. Y.S.
간행물명
Journal of electrochemical science and technology
권/호정보
2012년|3권 2호|pp.72-79 (8 pages)
발행정보
한국전기화학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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$Li_2MnSiO_4$ was synthesized using the solid-state method under an Ar atmosphere at three different calcination temperatures (900, 950, and $1000^{circ}C$). The optimization of the carbon coating was also carried out using various molar concentrations of adipic acid as the carbon source. The XRD pattern confirmed that the resulting $Li_2MnSiO_4$ particles exhibited an orthorhombic structure with a $Pmn2_1$ space group. Cyclic voltammetry was utilized to investigate the capacitive behavior of $Li_2MnSiO_4$ along with activated carbon (AC) in a hybrid supercapacitor with a two-electrode cell configuration. The $Li_2MnSiO_4$/AC cell exhibited a high discharge capacitance and energy density of $43.2Fg^{-1}$ and $54Whkg^{-1}$, respectively, at $1.0mAcm^{-2}$. The $Li_2MnSiO_4$/AC hybrid supercapacitor exhibited an excellent cycling stability over 1000 measured cycles with coulombic efficiency over > 99 %. Electrochemical impedance spectroscopy was conducted to corroborate the results that were obtained and described.