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Ce가 첨가된 Pt/γ-Al2O3 촉매의 선택적 CO 산화반응 특성
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  • Ce가 첨가된 Pt/γ-Al2O3 촉매의 선택적 CO 산화반응 특성
저자명
김기혁,구기영,정운호,윤왕래,Kim. Kihyeok,Koo. Keeyoung,Jung. Unho,Yoon. Wanglai
간행물명
한국수소 및 신에너지학회 논문집
권/호정보
2012년|23권 6호|pp.640-646 (7 pages)
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한국수소및신에너지학회
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

The effect of Ce promotion over 1wt% $Pt/{gamma}-Al_2O_3$ catalysts on the CO conversion and $CO_2$ selectivity was investigated in preferential CO oxidation (PrOx) to reduce the CO concentration less than 10 ppm in excess $H_2$ stream for polymer electrolyte membrane fuel cell (PEMFC). Ce-promoted 1wt% $Pt/{gamma}-Al_2O_3$ catalysts were prepared by incipient wetness impregnation method and the loading amount of Pt was fixed at 1wt%. The content of Ce promoter which has excellent oxygen storage and transfer capability due to the redox property was adjusted from 0 to 1.5wt%. Ce-promoted 1wt% $Pt/{gamma}-Al_2O_3$ catalysts exhibit high CO conversion and $CO_2$ selectivity at low temperatures below $150^{circ}C$ due to the improvement of reducibility of surface PtOx species compared with the 1wt% $Pt/{gamma}-Al_2O_3$ catalyst without Ce addition. When Ce content was more than 1wt%, the catalytic activity was decreased at over $160^{circ}C$ in PrOx because of competitive $H_2$ oxidation. As a result, 0.5wt% Ce is optimal content not only to achieve high catalytic activity and good stability at low temperatures below $150^{circ}C$ in the presence of $CO_2$ and $H_2O$ but also to minimize the $H_2$ oxidation at high temperatures.