This paper describes the process of optimal resonant frequency design with full-bridge series-loaded resonant dc-dc converter in a high efficiency 3.3 kW on-board battery charger application for Electric Vehicles and Plug-in Hybrid Electric Vehicles. The optimal range of resonant frequency and switching frequency used for ZVS are determined by considering trade-off between loss of switching devices and resonant network with size of passive/magnetic devices. In addition, it is defined charging region of battery, the load of on-board charger, as the area of load by deliberating the characteristic of resonant. It is verified the designed frequency band by reflecting the defined area on resonant frequency.