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Hyperpolarized 129 NMR Study of TiO2 Nanotubes
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취소
  • Hyperpolarized 129 NMR Study of TiO2 Nanotubes
  • Hyperpolarized 129 NMR Study of TiO2 Nanotubes
저자명
Lee. Sang-Man,Lee. Soon-Chang,Mehrotra. Vandana,Kim. Hae-Jin,Lee. Hee-Cheon
간행물명
Bulletin of the Korean Chemical Society
권/호정보
2012년|33권 2호|pp.511-514 (4 pages)
발행정보
대한화학회
파일정보
정기간행물|ENG|
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기타
이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

A continuous flow hyperpolarized (HP) $^{129}Xe$ NMR spectroscopy was employed for the first time to investigate $TiO_2$ nanotubes (Ti-NTs) synthesized from commercial nanoparticles with different reaction times. A single peak attributing to channels for Ti-NTs was observed for variable temperature HP $^{129}Xe$ NMR spectra. It was also noted that there is alteration in value for heat of adsorption, ${Delta}H$ from $12.6{pm}1.3$ to $16.4{pm}0.4kJ/mol$ and variation in chemical shift of the xenon adsorbed in channels, ${delta}_s$ from $120{pm}2sim135{pm}9ppm$ which were closely correlated to channel length and it was shown that P25-24 Ti-NTs with longest channel is most favorite Ti-NTs for Xe adsorption.