Recently due to the increasing of the importance on the green energy is getting higher by implementing EERS(Energy Efficiency Resource Standards) and NA(Negotiated Agreement) such as lacks of natural resources and The United Nations Framework Convention on Climate Change. And the most practical solution is CHP(Combined Heat and Power) which performs the best energy efficiency. This paper developed optimal operation mechanism of CES(Community Energy System) for enhancement of energy efficiency using CHP(Combined Heat and Power), PLB(Peak Load Boiler) and ACC(ACCumulator) capacities. This method optimally operated these capacities calculated the maximum profits by Dynamic Programing. Through the case studies, it is verified that the proposed algorithm of can evaluate availability.