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Accumulation and Decay of Macroscopic Correlations in Elementary Reactions Kinetics
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  • Accumulation and Decay of Macroscopic Correlations in Elementary Reactions Kinetics
  • Accumulation and Decay of Macroscopic Correlations in Elementary Reactions Kinetics
저자명
Doktorov. Alexander B.,Kipriyanov. Alexander A.,Kipriyanov. Alexey A.
간행물명
Bulletin of the Korean Chemical Society
권/호정보
2012년|33권 3호|pp.941-952 (12 pages)
발행정보
대한화학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
서지반출

기타언어초록

In the present contribution the Encounter Theory (ET) (the prototype of the classical Collision Theory in rarefied gases) concepts for widely occurring diffusion assisted irreversible bulk reactions A + A ${ ightarrow}$ C and A + B ${ ightarrow}$ C in liquid solutions examined by the authors in the literature are analyzed and compared with each other for these different types of reactions. It is shown that for a particular case of equal initial concentrations $[A]_0=[B]_0$ in the reaction A + B ${ ightarrow}$ C, when the kinetics of both reactions A + A ${ ightarrow}$ C and A + B ${ ightarrow}$ C in the framework of formal chemical kinetics and ET are the same, the accumulation of macroscopic correlations breaking the concepts of independent encounters and leading to the Generalized Encounter Theory (GET) are drastically different. The influence of the force interaction and the decay of nonstable reactants on the time behavior the macroscopic correlations is also briefly discussed.