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Direct Calculation Method for Excited-state Diffusion-influenced Reversible Reactions with an External Field
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  • Direct Calculation Method for Excited-state Diffusion-influenced Reversible Reactions with an External Field
  • Direct Calculation Method for Excited-state Diffusion-influenced Reversible Reactions with an External Field
저자명
Reigh. Shang Yik,Kim. Hyo-Joon
간행물명
Bulletin of the Korean Chemical Society
권/호정보
2012년|33권 3호|pp.1015-1019 (5 pages)
발행정보
대한화학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

The direct calculation method is generalized to the excited-state diffusion-influenced reversible reaction of a neutral and a charged particle under an external field with two different lifetimes and quenching in three dimensions. The present method provides an alternative way to calculate the binding probability density functions and the survival probabilities from the corresponding irreversible results. The solutions are obtained as the series solutions by the diagonal approximation due to the anisotropy of the unidirectional external field. The numerical results are found to be in good agreement with those of the previous study [S. Y. Reigh et al. J. Chem. Phys. 132, 164112 (2010)] within a weak field limit. The solutions of two approaches show qualitatively the same overall behavior including the power laws at long times.