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Stearic acid로 표면 코팅된 탄산칼슘의 폴리프로필렌에서의 분산
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  • Stearic acid로 표면 코팅된 탄산칼슘의 폴리프로필렌에서의 분산
저자명
송준영,정연수,함민경,곽영제,정영진,Song. Junyoung,Jung. Yoen-Su,Ham. Min-Kyoung,Kwark. Young-Je,Jeong. Young-Jin
간행물명
韓國纖維工學會誌
권/호정보
2012년|49권 3호|pp.169-173 (5 pages)
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한국섬유공학회
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

Calcium carbonate ($CaCO_3$) with 15~40 nm average diameter was compounded with polypropylene (PP) in a melted state to form composite materials. To enhance the dispersibility in PP, the surface of the $CaCO_3$ was coated with hydrophobic stearic acid (SA). The SA-coated $CaCO_3$ (SA-$CaCO_3$) showed hydrophobic nature, which resulted in rapid precipitation in water. When melt-compounded with PP, SA-$CaCO_3$ was uniformly distributed throughout the PP matrix, while the uncoated $CaCO_3$ formed aggregated structures in the PP. At up to 5 wt% of SA-$CaCO_3$ content, the composites showed well-dispersed structure, although some level of aggregation was observed in the composites with 10 wt% of SA-$CaCO_3$. The dispersibility improved with a repeated process of compounding. The melting and crystallization temperatures of PP increased with incorporation of $CaCO_3$. The enthalpy of the transitions also increased and the full-width of half maximum of the crystallization peak decreased. However, SA-coating did not produce additional effects on the crystallization behavior of PP. These results showed that the $CaCO_3$ acted as crystal nuclei.