- Stearic acid로 표면 코팅된 탄산칼슘의 폴리프로필렌에서의 분산
- ㆍ 저자명
- 송준영,정연수,함민경,곽영제,정영진,Song. Junyoung,Jung. Yoen-Su,Ham. Min-Kyoung,Kwark. Young-Je,Jeong. Young-Jin
- ㆍ 간행물명
- 韓國纖維工學會誌
- ㆍ 권/호정보
- 2012년|49권 3호|pp.169-173 (5 pages)
- ㆍ 발행정보
- 한국섬유공학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
Calcium carbonate ($CaCO_3$) with 15~40 nm average diameter was compounded with polypropylene (PP) in a melted state to form composite materials. To enhance the dispersibility in PP, the surface of the $CaCO_3$ was coated with hydrophobic stearic acid (SA). The SA-coated $CaCO_3$ (SA-$CaCO_3$) showed hydrophobic nature, which resulted in rapid precipitation in water. When melt-compounded with PP, SA-$CaCO_3$ was uniformly distributed throughout the PP matrix, while the uncoated $CaCO_3$ formed aggregated structures in the PP. At up to 5 wt% of SA-$CaCO_3$ content, the composites showed well-dispersed structure, although some level of aggregation was observed in the composites with 10 wt% of SA-$CaCO_3$. The dispersibility improved with a repeated process of compounding. The melting and crystallization temperatures of PP increased with incorporation of $CaCO_3$. The enthalpy of the transitions also increased and the full-width of half maximum of the crystallization peak decreased. However, SA-coating did not produce additional effects on the crystallization behavior of PP. These results showed that the $CaCO_3$ acted as crystal nuclei.