A diesel-Liquefied natural gas(LNG) combustion engine truck fleet demonstration project had been carried out and commercial expansion project was launched. The key issues of these projects are the safety of LNG fuel station and the reduction of natural gas relief. When LNG is fueled to LNG vehicles the heat is input in the LNG system. The LNG in the fueling system was boiled and the vapor of LNG is vented through the safety devices. The temperature of the vapor of LNG is $-108^{circ}C$ and density is heavier than air. It can be dispersed to downside of the fuel station. The safety evaluation is carried out using CFD program and risk assessment program for the vapor of LNG in the LNG vehicle fuel station. The hazards are identified and suggested the operation instruction to reduce the relief of LNG vapor.