In this research, a sewage sludge solubilization study using electrolysis was performed as a pre-treatment for anaerobic digestion efficiency improvement. SCOD potency increased as the treatment time and electric current density increased with sludge electrolysis treatment while SCOD, TN, and TP especially showed the highest increase of 7.4 times, 1.9 times, and 1.3 times respectively at the 60 minute point of treatment. Solubilization was high at the strong acidic and alkaline status for the sewage sludge electrolysis treatment results along early stage pH, and especially, a high solubilization percentage of 32.9% was seen at pH 12. The above result shows that there was an increase of organic matter able to be used by microorganisms from sludge floc and the destruction of EPS structure due to direct and indirect oxidation following electrolysis.