Homogeneous charge compression ignition (HCCI) engines have the potential to raise the efficiency of reciprocating engines during partial load operation. However, the performance of the HCCI engine at high loads is restricted by severe knocking, which can be observed by the excessive pressure rise rate. This is due to the rapid combustion process occurring inside the cylinder, which does not follow the flame propagation that is seen in conventional engines. In this study, a low compression ratio of 9.5:1 for a gasoline engine was converted to operate in HCCI mode with the goal being to expand the stable operating region at high loads. Initially, pure n-heptane was used as the fuel at equivalence ratios of 0.30 to 0.58 with elevated intake charge temperatures of 180 and $90^{circ}C$, respectively. The n-heptane HCCI engine could reach a maximum performance at an indicated mean effective pressure (IMEP) of 0.38 MPa, which was larger than the performance found in the literature. To reach an even higher performance, a dual-fuel system was exploited. Methanol, as an anti-detonant additive, was introduced into the intake stream with various amounts of n-heptane at fixed equivalence ratios in the range of 0.42 to 0.52. It was found that the methanol addition cooled the mixture down prior to combustion and resulted in an increased coefficient of variation (COV). In order to maintain stable combustion and keep the pressure rise rate below the limit, the intake charge temperature should be increased. Introduction of 90% and 95% (vol/vol) hydrous methanol showed a similar trend but a lower thermal conversion efficiency and IMEP value. Therefore, a dual fuel HCCI engine could maintain a high thermal conversion efficiency across a wide load and enhance a 5% larger load compared to a pure n-heptane-fuelled HCCI engine. The hydrocarbon (HC) and carbon monoxide (CO) emissions were lower than 800 ppm and 0.10%, respectively. They were less at higher loads. The nitrogen oxides ($NO_x$) emissions were below 12 ppm and were found to increase sharply at higher loads to a maximum of 23 ppm.