To simulate more realistic networks, we introduce a complex dynamical network model with double non-delayed and double delayed coupling and further investigate its synchronization phenomenon in this paper. Based on Lyapunov stability theory, adaptive synchronization criteria is obtained. Analytical result shows that under the designed adaptive controllers, the complex dynamical network with double non-delayed and double delayed coupling can asymptotically synchronize to a given trajectory. What is more, the coupling matrix is not assumed to be symmetric or irreducible. Finally, simulation results show the method is effective.