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Isospecific Polymerizations of 1-Butene Catalyzed by $MgCl_2/TiCl_4$/Internal Donor-$AlR_3$/External Donor System
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  • Isospecific Polymerizations of 1-Butene Catalyzed by $MgCl_2/TiCl_4$/Internal Donor-$AlR_3$/External Donor System
  • Isospecific Polymerizations of 1-Butene Catalyzed by $MgCl_2/TiCl_4$/Internal Donor-$AlR_3$/External Donor System
저자명
Ren. Hegang,Yang. Min,Zhang. Baojun,Ren. Xiaofei,Liu. Binyuan,Wang. Yanji,Kim. Il
간행물명
Macromolecular research
권/호정보
2012년|20권 9호|pp.985-989 (5 pages)
발행정보
한국고분자학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

1-Butene polymerizations were carried out by using a $MgCl_2/TiCl_4/ID-AlR_3$/ED catalyst system in n-hexane, therein the internal donor (ID) is diisobutyl phthalate (DIBP), the external donor (ED) is diphenyl dimethoxysilane (DDS) or cyclohexyl methyl dimethoxysilane (CHMMS), and the $AlR_3$ activator is $AlEt_3$ or $Al(i-Bu)_3$. The effect of the molar ratio of DIBP/Mg and polymerization conditions on the catalytic activity and the isotactic index (II) of poly(1-butene) (PB) was investigated. The dosage of DIBP remarkably improved the catalytic activity and the II of PB. CHMMS was more effective than DDS for increasing the II of PB. The addition of a small amount of hydrogen enhanced the catalytic activity from 15.1 to 17.5 kg-$PB{cdot}gTi^{-1}$ and the II value of PB from 89.3% to 95.1%. The mixture of $AlR_3$ was beneficial to increase the catalytic activity with negligible effect on the isospecificity.