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Compatibility and Physical Properties of Poly(lactic acid)/Poly(ethylene terephthalate glycol) Blends
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  • Compatibility and Physical Properties of Poly(lactic acid)/Poly(ethylene terephthalate glycol) Blends
  • Compatibility and Physical Properties of Poly(lactic acid)/Poly(ethylene terephthalate glycol) Blends
저자명
Park. Jun Yong,Hwang. Sung Yeon,Yoon. Won Jae,Yoo. Eui Sang,Im. Seung Soon
간행물명
Macromolecular research
권/호정보
2012년|20권 12호|pp.1300-1306 (7 pages)
발행정보
한국고분자학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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Blends of poly(lactic acid) (PLA) and poly(ethylene terephthalate glycol) (PETG) of various compositions were prepared by melt compounding and their compatibilities, physical properties, and isothermal crystallization behaviors were investigated. The calculated solubility parameters of PETG are similar to those of PLA. The interaction parameter between PLA and PETG was derived from the Flory-Huggins theory and predicted that PLA and PETG are miscible when PETG contents are below 22 wt%. In accordance with this result, the tan ${delta}$ peak and glass transition temperatures of blends determined from dynamic mechanical analysis (DMA) and differential scanning calorimetry (DSC) showed a single peak at PETG contents lower than 22 wt%. Tensile test results showed that the elongation at the break of blends increased with an increase in PETG content. DSC and isothermal crystallization results showed that PETG accelerates the crystallization rate of PLA at PETG contents lower than 22 wt%, indicating that PETG acts as a nucleation agent in the crystallization of PLA. Wide angle X-ray diffraction results (WAXD) showed that the crystalline structure of PLA is not affected by the incorporation of PETG.