In this paper, a solar energy powered bicycle linked to a wireless sensor network (WSN) which monitors the transfer of solar energy to an electrical energy storage unit and an analysis of its effectiveness is proposed. In order to achieve this goal, a solar-powered bicycle with an attached ZigBee and a far-end wireless network supervisory system is setup. Experimental results prove that our prototype, solar energy powered bicycle, can achieve enough solar energy for charging a two lead-acid battery pack. As a result, the user, through use of a wireless network in the parking period can be kept aware of the data on the amount of immediate solar radiation, the degree of illumination, the ambient temperature, and electrical energy storage capacity information of the bicycle through an internet interface.